Sunday 28 October 2012

Second Law Of Thermodynamics

The second law of thermodynamics states that “in general, the total entropy of any system will not decrease other than by increasing the entropy of some other system.”

Entropy is defined as a “thermodynamic property that is the measure of a system’s thermal energy per unit temperature that is unavailable for doing useful work”.

A common example of increasing entropy is ice melting in a warm room, described in 1862 by Rudolf Clausius as an increase in the “disgregation” (the magnitude of the degree in which the molecules of a body are separated from each other) of the water molecules in ice: order leading to disorder (more random).

In a system isolated from the environment, the entropy of that system will tend to not decrease. In addition, it is impossible for any device operating on a cycle to produce net work from a single temperature reservoir. The production of net work requires flow of heat from a hotter to colder reservoir. As a result, there is no perpetual motion system. A reduction in the increase of entropy in a specific process, such as a chemical reaction, means that it is energetically more efficient.

The entropy of a system that is not isolated may decrease. For example, an air conditioner may cool the air in a room, reducing the entropy of the air in the room. The heat expelled from the room, which the air conditioner transports and discharges to the outside air, will always make a bigger contribution to the entropy of the environment than will decrease the entropy of the air in the room. Therefore, the total entropy of the room plus the entropy of the environment increases. This example proves the second law of thermodynamics.

References

Second law of thermodynamics. (n.d.). Retrieved from http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/seclaw.html

Benson, T. (2008, July 11). Second law of thermodynamics. Retrieved from http://www.grc.nasa.gov/WWW/k-12/airplane/thermo2.html

Laws of thermodynamics. (2010, May 18). Retrieved from http://www.emc.maricopa.edu/faculty/farabee/biobk/biobookener1.html

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